An outboard Tstat should open around 143 F. to keep the temperature within safe limits. Above 160 F or so, salts and minerals in the water can leach out and build up deposits in the water jackets. This is why only TCW III (Two Cycle, Water Cooled) marine oil should be used in an outboard motor as it is designed to burn off at the lower operating temperatures.
When you check your motors temperature, you’ll find hot spots and cold spots but generally the top of the block and on the starboard side where the welch plug is are good places to check.