I’m not sure I understand what you are describing. Are there broken head bolt shanks still stuck in the head? If so, is there more than one broken head bolt stud? If there is only one broken stud, you can smack on the other side of the head with a heavy plastic mallet which will cause the whole head to rotate, hopefully loosening the one broken stud as well.
You must be very careful trying to wedge something between the head and block, the head is unlikely to give way if broken studs are holding it in place, damage to the cylinder deck is inevitable.
I just can’t imagine anything holding that head in place if there are no broken studs, unless someone used JB weld or something else like that to glue the head down. You may want to consider finding a used head, then you can sacrifice the head in order to be sure you do no damage to the cylinder deck. Simply take an air chisel to the head outside the broken/seized stud(s) which will split the head open and loosen the salty grip.